\(xMnO_4^ – + y{C_2}O_4^{2 – } + z{H^ + } \to xM{n^{2 + }} + 2yC{O_2} + \frac{z}{2}{H_2}O\)

Consider the following reaction:

The values of x, y and z in the reaction are, respectively:

(1) 5, 2 and 16        (2) 2, 5 and 8        (3) 2, 5 and 16        (4) 5, 2 and 8

[JEE Main 2013]

Solution

We have, [Reduction]

[Oxidation]

On balancing,

………….(1)

………….(2)

2. (1) + 5. (2)

So,

Balancing O and H considering acidic medium (since H+ is mentioned),

x = 2, y = 5, z = 16

Hence, (3).

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